48) Assembly of 2-Substituted Tetrahydroquinolines from ortho-Methylbenzenesulfamides and Dienes, Using a C(sp3)–H Activation/Annulation Sequence

I. Huertas-Morales, B. Cendón, D. Costa, J. L. Mascareñas, M. Gulías

Org. Lett., 2024, 26, 7789–7794

47) Axially Chiral 2-Hydroxybiaryls by Palladium-Catalyzed Enantioselective C–H Activation

P. Losada, L. Goicoechea, J. L. Mascareñas, M. Gulías

ACS Catal., 2023, 13, 13994–13999

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46) Metal-Catalyzed Annulations via Activation of Alkenyl C-H Bonds

B. Cendón, J. González, J. L. Mascareñas, M. Gulías

Handbook of CH-Functionalization (CHF), 2022, Diverse Functionalizations, 202

45) Chiral Ligands Based on Binaphthyl Scaffolds for Pd-Catalyzed Enantioselective C–H Activation/Cycloaddition Reactions

J. González, X. Vidal, M. Ortuño, J. L. Mascareñas, M. Gulías

J. Am. Chem. Soc., 2022, 144, 21437–21442

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44) CHF-0138: Transition metal-catalyzed desymmetrizations based on C–H activation processes

M. Font, X. Vidal, M. Gulías, J. L. Mascareñas

Handbook of CH-Functionalization (CHF), 2022, 1, 1-47

43) Transition-Metal-Catalyzed Annulations Involving the Activation of C(sp3)-H Bonds

M. Font, M. Gulías, J. L. Mascareñas

Angew. Chem. Int. Ed., 2022, 60, e202112848

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42) (4 + 2) Cycloadditions via Pd C(sp3)–H activation

X. Vidal, M. Font, B. Cendón, J. L. Mascareñas, M. Gulías

Trends Chem., 2021, 3, 1102-1103

41) Assembly of Tetrahydroquinolines and 2-Benzazepines by Pd-Catalyzed Cycloadditions Involving the Activation of C(sp3)–H Bonds

X. Vidal, J. L. Mascareñas, M. Gulías

Org. Lett., 2021, 23, 5323–5328

40) Rhodium(III)-catalyzed formal cycloaddition between thienopyridine/thienopyrazine carboxylic acids and alkynes, triggered by C-H activation

J. M. Rodrigues, B. Cendón, M. Gulías, J. L. Mascareñas, M. Queiroz

EurJOC, 2021, 2021, 3234-3240

39) Kinetic Resolution of Allyltriflamides through a Pd-Catalyzed C–H Functionalization with Allenes: Asymmetric Assembly of Tetrahydropyridines

J. González, B. Cendón, J. L. Mascareñas, M. Gulías

J. Am. Chem. Soc., 2021, 143, 3747-3752

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38) Photocatalytic Trifluoromethoxylation of Arenes and Heteroarenes in Continuous-Flow

Nyuchev, A. V, Wan, T., B. Cendón, Sambiagio, C., Struijs, J. J. C, Ho, M., M. Gulías, Wang, Y. , Noël, T.

Beilstein J. Org. Chem., 2020, 16, 1305–1312

37) Palladium-catalyzed formal (4+2) cycloaddition between alkyl amides and dienes initiated by the activation of C(sp3)−H bonds

B. Cendón, M. Font, J. L. Mascareñas, M. Gulías

ACS Catal., 2020, 10, 3425-3430

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36) Practical, Large-Scale Preparation of Benzoxepines and Coumarins through Rhodium(III)-Catalyzed C–H Activation/Annulation Reactions

M. Gulías, D. Marcos-Atanes, J. L. Mascareñas, M. Font

Org. Process. Res. Dev., 2019, 23, 1669-1673

35) Rhodium(III)-catalyzed intramolecular annulations of acrylic and benzoic acids to alkynes

D. Fernández, N. Casanova, J. L. Mascareñas, M. Gulías

ACS Omega, 2019, 4, 6257−6263

34) Palladium-catalyzed, enantioselective formal cycloaddition between benzyltriflamides and allenes: Straightforward access to enantioen-riched isoquinolines

X. Vidal, J. L. Mascareñas, M. Gulías

J. Am. Chem. Soc., 2019, 141, 1862–1866

33) Rhodium-catalyzed annulation of ortho-alkenylanilides with alkynes: Formation of unexpected naphthalene adducts

A. Seoane, C. Comanescu, N. Casanova, R. García-Fandiño, X. Diz, J. L. Mascareñas, M. Gulías

Angew. Chem. Int. Ed., 2019, 58, 1700-1704

32) Iridium(I)-Catalyzed Intramolecular Cycloisomerization of Enynes: Scope and Mechanistic Course

D. Fernández, C. A. B. Rodrigues, M. Calvelo, M. Gulías, J. L. Mascareñas, F. López

ACS Catal., 2018, 8, 7397–7402

31) Enantioselective Palladium-Catalyzed [3C + 2C] and [4C + 3C] Intramolecular Cycloadditions of Alkylidenecyclopropanes

F. Verdugo, L. Villarino, J. Durán, M. Gulías, J. L. Mascareñas, F. López

ACS Catal., 2018, 8, 6100-6105

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30) Rhodium(III)‐Catalyzed Annulation of 2‐Alkenylanilides with Alkynes via C‐H Activation: a Direct Access to 2‐substituted Indolines

M. Font, B. Cendón, A. Seoane, J. L. Mascareñas, M. Gulías

Angew. Chem. Int. Ed., 2018, 57, 8255-8259

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29) Iridium(I)-Catalyzed Intramolecular Hydrocarbonation of Alkenes: Efficient Access to Cyclic Systems Bearing Quaternary Stereocenters

D. Fernández, M. Gulías, J. L. Mascareñas, F. López

Angew. Chem. Int. Ed., 2017, 56, 9641-4645

Highlighted in chemistry views: http://www.chemistryviews.org/details/ezine/10593553/Iridium-Catalyzed_CH_Functionalization.html

28) Palladium-Catalyzed Formal (5 + 2) Annulation between ortho-Alkenylanilides and Allenes

B. Cendón, N. Casanova, C. Comanescu, R. García-Fandiño, A. Seoane, M. Gulías, J. L. Mascareñas

Org. Lett., 2017, 19, 1674-1677

27) Concise, Enantioselective, and Versatile Synthesis of (-)-Englerin A. Based on a Platinum-Catalyzed [4C+3C] Cycloaddition of Allenedienes

R. Nelson, M. Gulías, J. L. Mascareñas, F. López

Angew. Chem. Int. Ed., 2016, 55 (46), 14359-14363

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26) Metal-Catalyzed Annulations through Activation and Cleavage of C-H Bonds

M. Gulías, J. L. Mascareñas

Angew. Chem. Int. Ed., 2016, 55, 11000-11019

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25) Palladium(II)-Catalyzed Annulation between ortho-Alkenylphenols and Allenes. Key Role of the Metal Geometry in Determining the Reaction Outcome

N. Casanova, K. P. Del Rio, R. García-Fandiño, J. L. Mascareñas, M. Gulías

ACS Catal., 2016, 6 (5), 3349–3353

24) Amide-Directed Formation of Five-Coordinate Osmium Alkylidenes from Alkynes

N. Casanova, M. Á. Esteruelas, M. Gulías, C. Larramona, J. L. Mascareñas, E. Oñate

Organometallics, 2016, 35, 91-99

23) Rhodium-Catalyzed (5+1) Annulations Between 2-Alkenylphenols and Allenes: A Practical Entry to 2,2-Disubstituted 2H-Chromenes

N. Casanova, A. Seoane, J. L. Mascareñas, M. Gulías

Angew. Chem. Int. Ed., 2015, 54, 2374-2377

22) Rhodium(III)-Catalyzed Dearomatizing (3 + 2) Annulation of 2-Alkenylphenols and Alkynes

A. Seoane, N. Casanova, N. Quiñones, J. L. Mascareñas, M. Gulías

J. Am. Chem. Soc., 2014, 136(21), 7607-7610

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21) Straightforward Assembly of Benzoxepines by Means of a Rhodium(III)-Catalyzed C–H Functionalization of o-Vinylphenols

A. Seoane, N. Casanova, N. Quiñones, J. L. Mascareñas, M. Gulías

J. Am. Chem. Soc., 2014, 136(3), 834–837

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20) Rhodium-catalyzed Intramolecular (3+2+2) Cycloadditions between Alkylidenecyclopropanes, Alkynes and Alkenes

M. Araya, M. Gulías, I. Fernández, G. Barghava, L. Castedo, J. L. Mascareñas, F. López

Chem. Eur. J., 2014, 20, 10255-10259

19) (4+3) Cycloadditions

F. López, M. Gulías, J. L. Mascareñas

Comprehensive Organic Synthesis II. Ed: Elsevier, Volumen: 5. “Combining C-C π-Bonds”, 2014, 5, 595-655

18) Rhodium(III)-catalyzed intramolecular annulations involving amide-directed C-H activations: synthetic scope and mechanistic studies

N. Quiñones, A. Seoane, R. García-Fandiño, J. L. Mascareñas, M. Gulías

Chem. Sci., 2013, 4, 2874-2879

17) Mechanistic study on the palladium-catalyzed (3+2) intramolecular cycloaddition of alk-5-enylidenecyclopropanes

R. García-Fandiño, M. Gulías, J. L. Mascareñas, D. Cárdenas

Dalton Trans., 2012, 41, 9468-9481

16) Reactions of an Osmium(IV) Complex with Allenedienes: Coordination and Intramolecular Cycloadditions

A. Collado, M. Á. Esteruelas, M. Gulías, J. L. Mascareñas, E. Oñate

Organometallics, 2012, 31, 4450-4458

15) Ruthenium-catalyzed (2+2) Intramolecular Cycloaddition of Allenenes

M. Gulías, A. Collado, B. Trillo, F. López, E. Oñate, M. Á. Esteruelas, J. L. Mascareñas

J. Am. Chem. Soc., 2011, 133, 7660-7663

14) Development of transition-metal-catalyzed cycloaddition reactions leading to polycarbocyclic systems

M. Gulías, F. López, J. L. Mascareñas

Pure App. Chem., 2011, 83, 495-506

13) Amine directed Pd(II)-catalyzed C–H bond functionalization under ambient conditions

B. Haffemayer, M. Gulías, M. J. Gaunt

Chem. Sci., 2011, 2, 312-315

12) Palladium(II)-Catalyzed C-H Bond Arylation of Electron-Deficient Arenes at Room Temperature

M. J. Tredwell, M. Gulías, N. G. Bremeyer, C. C. Johansson, B. S. Collins, M. J. Gaunt

Angew. Chem. Int. Ed., 2011, 50, 1076-1079

11) Nickel-Catalyzed [3+2+2] Cycloadditions between Alkynylidenecyclopropanes and Activated Alkenes

L. Saya, G. Barghava, M. Á. Navarro, M. Gulías, F. López, I. Fernández, L. Castedo, J. L. Mascareñas

Angew. Chem. Int. Ed., 2010, 49, 9886-9890

10) Oxidative Pd(II)-Catalyzed C-H Bond Amination to Carbazole at Ambient Temperature

J. Jordan-Hore, C. C. Johansson, M. Gulías, E. M. Beck, M. J. Gaunt

J. Am. Chem. Soc., 2008, 130, 16184-16186

9) Palladium-catalysed [3 + 2] cycloaddition of alk-5-ynylidenecyclopropanes to alkynes: a mechanistic DFT study

R. García-Fandiño, M. Gulías, L. Castedo, J. R. Granja, J. L. Mascareñas, D. Cárdenas

Chem. Eur. J., 2008, 14, 272-281

8) Platinum-catalyzed intramolecular [4C + 3C] cycloaddition between dienes and allenes

B. Trillo, F. López, M. Gulías, L. Castedo, J. L. Mascareñas

Angew. Chem. Int. Ed., 2008, 47, 951-954

7) Palladium-catalyzed [4 + 3] intramolecular cycloaddition of alkylidenecyclopropanes and dienes

M. Gulías, J. Durán, F. López, L. Castedo, J. L. Mascareñas

J. Am. Chem. Soc., 2007, 129, 11026-11027

6) Palladium-catalyzed [3+2] intramolecular cycloaddition of alk-5-enylidenecyclopropanes

M. Gulías, R. García-Fandiño, A. Delgado, L. Castedo, J. L. Mascareñas

J. Am. Chem. Soc., 2006, 128, 384-385

5) Palladium-catalyzed intramolecular [3C+2C] cycloaddition of alkylidenecyclopropanes to allenes

B. Trillo, M. Gulías, F. López, L. Castedo, J. L. Mascareñas

Adv. Synth. Catal., 2006, 348, 2381-2384

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4) Ligand-Induced Acceleration of the Intramolecular [3 + 2] Cycloaddition between Alkynes and Alkylidenecyclopropanes

J. Durán, M. Gulías, L. Castedo, J. L. Mascareñas

Org. Lett., 2005, 7, 5693-5696

3) Divergent reactivity of alk-5-ynylidenecyclopropanes in the presence of the first or the second generation Grubbs' catalysts

B. Trillo, M. Gulías, F. López, L. Castedo, J. L. Mascareñas

J. Organomet. Chem., 2005, 690, 5609-5615

2) Regioselectivity Control in a Ruthenium-Catalyzed Cycloisomerization of Diyne-ols

B. T. Trost, M. T. Rudd, M. Gulías, P. I. Lee, A. E. Pomerantz

Org. Lett., 2004, 6, 4235-4238

1) Synthesis of fused Oxabicyclic Systems by Metal-Catalyzed Intramolecular Adddition of 1,3-Cycloalkanediones to Alkynes

M. Gulías, J. R. Rodríguez, L. Castedo, J. L. Mascareñas

Org. Lett., 2003, 5, 1975-1977