Publications

2019

36) Practical, Large-Scale Preparation of Benzoxepines and Coumarins through Rhodium(III)-Catalyzed C–H Activation/Annulation Reactions

M. Gulías, D. Marcos-Atanes, J. L. Mascareñas, M. Font

Org. Process. Res. Dev., 2019, 23, 1669-1673

36) Practical, Large-Scale Preparation of Benzoxepines and Coumarins through Rhodium(III)-Catalyzed C–H Activation/Annulation Reactions

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35) Rhodium(III)-catalyzed intramolecular annulations of acrylic and ben-zoic acids to alkynes

D. Fernández, N. Casanova, M. Gulías, J. L. Mascareñas

ACS Omega, 2019, 4, 6257−6263

35) Rhodium(III)-catalyzed intramolecular annulations of acrylic and ben-zoic acids to alkynes
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34) Palladium-catalyzed, enantioselective formal cycloaddition between benzyltriflamides and allenes: Straightforward access to enantioen-riched isoquinolines

X. Vidal, J. L. Mascareñas, M. Gulías

J. Am. Chem. Soc., 2019, 141, 1862–1866

34) Palladium-catalyzed, enantioselective formal cycloaddition between benzyltriflamides and allenes: Straightforward access to enantioen-riched isoquinolines
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33) Rhodium-catalyzed annulation of ortho-alkenylanilides with alkynes: Formation of unexpected naphthalene adducts

A. Seoane, C. Comanescu, N. Casanova, R. García-Fandiño, X. Diz, J. L. Mascareñas, M. Gulías

Angew. Chem. Int. Ed., 2019, 58, 1700-1704

33) Rhodium-catalyzed annulation of ortho-alkenylanilides with alkynes: Formation of unexpected naphthalene adducts
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2018

32) Iridium(I)-Catalyzed Intramolecular Cycloisomerization of Enynes: Scope and Mechanistic Course

D. Fernández, C. A. B. Rodrigues, M. Calvelo, M. Gulías, J. L. Mascareñas, F. López

ACS Catal., 2018, 8, 7397–7402

32) Iridium(I)-Catalyzed Intramolecular Cycloisomerization of Enynes: Scope and Mechanistic Course
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31) Enantioselective Palladium-Catalyzed [3C + 2C] and [4C + 3C] Intramolecular Cycloadditions of Alkylidenecyclopropanes

F. Verdugo, L. Villarino, J. Durán, M. Gulías, J. L. Mascareñas, F. López

ACS Catal., 2018, 8, 6100-6105

31) Enantioselective Palladium-Catalyzed [3C + 2C] and [4C + 3C] Intramolecular Cycloadditions of Alkylidenecyclopropanes

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30) Rhodium(III)‐Catalyzed Annulation of 2‐Alkenylanilides with Alkynes via C‐H Activation: a Direct Access to 2‐substituted Indolines

M. Font, B. Cendón, A. Seoane, J. L. Mascareñas, M. Gulías

Angew. Chem. Int. Ed., 2018, 57, 8255-8259

30) Rhodium(III)‐Catalyzed Annulation of 2‐Alkenylanilides with Alkynes via C‐H Activation: a Direct Access to 2‐substituted Indolines

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2017

29) Iridium(I)-Catalyzed Intramolecular Hydrocarbonation of Alkenes: Efficient Access to Cyclic Systems Bearing Quaternary Stereocenters

D. Fernández, M. Gulías, J. L. Mascareñas, F. López

Angew. Chem. Int. Ed., 2017, 56, 9641-4645

29) Iridium(I)-Catalyzed Intramolecular Hydrocarbonation of Alkenes: Efficient Access to Cyclic Systems Bearing Quaternary Stereocenters

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28) Palladium-Catalyzed Formal (5 + 2) Annulation between ortho-Alkenylanilides and Allenes

B. Cendón, N. Casanova, C. Comanescu, R. García-Fandiño, A. Seoane, M. Gulías, J. L. Mascareñas

Org. Lett., 2017, 19, 1674-1677

28) Palladium-Catalyzed Formal (5 + 2) Annulation between ortho-Alkenylanilides and Allenes
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2016

27) Concise, Enantioselective, and Versatile Synthesis of (-)-Englerin A. Based on a Platinum-Catalyzed [4C+3C] Cycloaddition of Allenedienes

R. Nelson, M. Gulías, J. L. Mascareñas, F. López

Angew. Chem. Int. Ed., 2016, 55 (46), 14359-14363

27) Concise, Enantioselective, and Versatile Synthesis of (-)-Englerin A. Based on a Platinum-Catalyzed [4C+3C] Cycloaddition of Allenedienes

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26) Metal-Catalyzed Annulations through Activation and Cleavage of C-H Bonds

M. Gulías, J. L. Mascareñas

Angew. Chem. Int. Ed., 2016, 55, 11000-11019

26) Metal-Catalyzed Annulations through Activation and Cleavage of C-H Bonds

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25) Palladium(II)-Catalyzed Annulation between ortho-Alkenylphenols and Allenes. Key Role of the Metal Geometry in Determining the Reaction Outcome

N. Casanova, K. P. Del Rio, R. García-Fandiño, J. L. Mascareñas, M. Gulías

ACS Catal., 2016, 6 (5), 3349–3353

25) Palladium(II)-Catalyzed Annulation between ortho-Alkenylphenols and Allenes. Key Role of the Metal Geometry in Determining the Reaction Outcome
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24) Amide-Directed Formation of Five-Coordinate Osmium Alkylidenes from Alkynes

N. Casanova, M. Á. Esteruelas, M. Gulías, C. Larramona, J. L. Mascareñas, E. Oñate

Organometallics, 2016, 35, 91-99

24) Amide-Directed Formation of Five-Coordinate Osmium Alkylidenes from Alkynes
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2015

23) Rhodium-Catalyzed (5+1) Annulations Between 2-Alkenylphenols and Allenes: A Practical Entry to 2,2-Disubstituted 2H-Chromenes

N. Casanova, A. Seoane, J. L. Mascareñas, M. Gulías

Angew. Chem. Int. Ed., 2015, 54, 2374-2377

23) Rhodium-Catalyzed (5+1) Annulations Between 2-Alkenylphenols and Allenes: A Practical Entry to 2,2-Disubstituted 2H-Chromenes
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2014

22) Rhodium(III)-Catalyzed Dearomatizing (3 + 2) Annulation of 2-Alkenylphenols and Alkynes

A. Seoane, N. Casanova, N. Quiñones, J. L. Mascareñas, M. Gulías

J. Am. Chem. Soc., 2014, 136(21), 7607-7610

22) Rhodium(III)-Catalyzed Dearomatizing (3 + 2) Annulation of 2-Alkenylphenols and Alkynes

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21) Straightforward Assembly of Benzoxepines by Means of a Rhodium(III)-Catalyzed C–H Functionalization of o-Vinylphenols

A. Seoane, N. Casanova, N. Quiñones, J. L. Mascareñas, M. Gulías

J. Am. Chem. Soc., 2014, 136(3), 834–837

21) Straightforward Assembly of Benzoxepines by Means of a Rhodium(III)-Catalyzed C–H Functionalization of o-Vinylphenols

TOP 5 of MOST READ ARTICLES in JACS in JANUARY 2014

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20) Rhodium-catalyzed Intramolecular (3+2+2) Cycloadditions between Alkylidenecyclopropanes, Alkynes and Alkenes

M. Araya, M. Gulías, I. Fernández, G. Barghava, L. Castedo, J. L. Mascareñas, F. López

Chem. Eur. J., 2014, 20, 10255-10259

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19) (4+3) Cycloadditions

F. López, M. Gulías, J. L. Mascareñas

Comprehensive Organic Synthesis II. Ed: Elsevier, Volumen: 5. “Combining C-C π-Bonds”, 2014, 5, 595-655

19) (4+3) Cycloadditions
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2013

18) Rhodium(III)-catalyzed intramolecular annulations involving amide-directed C-H activations: synthetic scope and mechanistic studies

N. Quiñones, A. Seoane, R. García-Fandiño, J. L. Mascareñas, M. Gulías

Chem. Sci., 2013, 4, 2874-2879

18) Rhodium(III)-catalyzed intramolecular annulations involving amide-directed C-H activations: synthetic scope and mechanistic studies
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2012

17) Mechanistic study on the palladium-catalyzed (3+2) intramolecular cycloaddition of alk-5-enylidenecyclopropanes

R. García-Fandiño, M. Gulías, J. L. Mascareñas, D. Cárdenas

Dalton Trans., 2012, 41, 9468-9481

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16) Reactions of an Osmium(IV) Complex with Allenedienes: Coordination and Intramolecular Cycloadditions

A. Collado, M. Á. Esteruelas, M. Gulías, J. L. Mascareñas, E. Oñate

Organometallics, 2012, 31, 4450-4458

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2011

15) Ruthenium-catalyzed (2+2) Intramolecular Cycloaddition of Allenenes

M. Gulías, A. Collado, B. Trillo, F. López, E. Oñate, M. Á. Esteruelas, J. L. Mascareñas

J. Am. Chem. Soc., 2011, 133, 7660-7663

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14) Development of transition-metal-catalyzed cycloaddition reactions leading to polycarbocyclic systems

M. Gulías, F. López, J. L. Mascareñas

Pure App. Chem., 2011, 83, 495-506

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13) Amine directed Pd(II)-catalyzed C–H bond functionalization under ambient conditions

B. Haffemayer, M. Gulías, M. J. Gaunt

Chem. Sci., 2011, 2, 312-315

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12) Palladium(II)-Catalyzed C-H Bond Arylation of Electron-Deficient Arenes at Room Temperature

M. J. Tredwell, M. Gulías, N. G. Bremeyer, C. C. Johansson, B. S. Collins, M. J. Gaunt

Angew. Chem. Int. Ed., 2011, 50, 1076-1079

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2010

11) Nickel-Catalyzed [3+2+2] Cycloadditions between Alkynylidenecyclopropanes and Activated Alkenes

L. Saya, G. Barghava, M. Á. Navarro, M. Gulías, F. López, I. Fernández, L. Castedo, J. L. Mascareñas

Angew. Chem. Int. Ed., 2010, 49, 9886-9890

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2008

10) Oxidative Pd(II)-Catalyzed C-H Bond Amination to Carbazole at Ambient Temperature

J. Jordan-Hore, C. C. Johansson, M. Gulías, E. M. Beck, M. J. Gaunt

J. Am. Chem. Soc., 2008, 130, 16184-16186

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9) Palladium-catalysed [3 + 2] cycloaddition of alk-5-ynylidenecyclopropanes to alkynes: a mechanistic DFT study

R. García-Fandiño, M. Gulías, L. Castedo, J. R. Granja, J. L. Mascareñas, D. Cárdenas

Chem. Eur. J., 2008, 14, 272-281

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8) Platinum-catalyzed intramolecular [4C + 3C] cycloaddition between dienes and allenes

B. Trillo, F. López, M. Gulías, L. Castedo, J. L. Mascareñas

Angew. Chem. Int. Ed., 2008, 47, 951-954

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2007

7) Palladium-catalyzed [4 + 3] intramolecular cycloaddition of alkylidenecyclopropanes and dienes

M. Gulías, J. Durán, F. López, L. Castedo, J. L. Mascareñas

J. Am. Chem. Soc., 2007, 129, 11026-11027

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2006

6) Palladium-catalyzed [3+2] intramolecular cycloaddition of alk-5-enylidenecyclopropanes

M. Gulías, R. García-Fandiño, A. Delgado, L. Castedo, J. L. Mascareñas

J. Am. Chem. Soc., 2006, 128, 384-385

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5) Palladium-catalyzed intramolecular [3C+2C] cycloaddition of alkylidenecyclopropanes to allenes

B. Trillo, M. Gulías, F. López, L. Castedo, J. L. Mascareñas

Adv. Synth. Catal., 2006, 348, 2381-2384

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2005

4) Ligand-Induced Acceleration of the Intramolecular [3 + 2] Cycloaddition between Alkynes and Alkylidenecyclopropanes

J. Durán, M. Gulías, L. Castedo, J. L. Mascareñas

Org. Lett., 2005, 7, 5693-5696

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3) Divergent reactivity of alk-5-ynylidenecyclopropanes in the presence of the first or the second generation Grubbs' catalysts

B. Trillo, M. Gulías, F. López, L. Castedo, J. L. Mascareñas

J. Organomet. Chem., 2005, 690, 5609-5615

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2004

2) Regioselectivity Control in a Ruthenium-Catalyzed Cycloisomerization of Diyne-ols

B. T. Trost, M. T. Rudd, M. Gulías, P. I. Lee, A. E. Pomerantz

Org. Lett., 2004, 6, 4235-4238

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2003

1) Synthesis of fused Oxabicyclic Systems by Metal-Catalyzed Intramolecular Adddition of 1,3-Cycloalkanediones to Alkynes

M. Gulías, J. R. Rodríguez, L. Castedo, J. L. Mascareñas

Org. Lett., 2003, 5, 1975-1977

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