2024
48) Assembly of 2-Substituted Tetrahydroquinolines from ortho-Methylbenzenesulfamides and Dienes, Using a C(sp3)–H Activation/Annulation Sequence
I. Huertas-Morales, B. Cendón, D. Costa, J. L. Mascareñas, M. Gulías
Org. Lett. , 2024 , 26 , 7789–7794
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2023
47) Axially Chiral 2-Hydroxybiaryls by Palladium-Catalyzed Enantioselective C–H Activation
P. Losada, L. Goicoechea, J. L. Mascareñas, M. Gulías
ACS Catal. , 2023 , 13 , 13994–13999
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2022
46) Metal-Catalyzed Annulations via Activation of Alkenyl C-H Bonds
B. Cendón, J. González, J. L. Mascareñas, M. Gulías
Handbook of CH-Functionalization (CHF) , 2022 , Diverse Functionalizations , 202
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45) Chiral Ligands Based on Binaphthyl Scaffolds for Pd-Catalyzed Enantioselective C–H Activation/Cycloaddition Reactions
J. González, X. Vidal, M. Ortuño, J. L. Mascareñas, M. Gulías
J. Am. Chem. Soc. , 2022 , 144 , 21437–21442
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44) CHF-0138: Transition metal-catalyzed desymmetrizations based on C–H activation processes
M. Font, X. Vidal, M. Gulías, J. L. Mascareñas
Handbook of CH-Functionalization (CHF) , 2022 , 1 , 1-47
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43) Transition-Metal-Catalyzed Annulations Involving the Activation of C(sp3)-H Bonds
M. Font, M. Gulías, J. L. Mascareñas
Angew. Chem. Int. Ed. , 2022 , 60 , e202112848
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2021
42) (4 + 2) Cycloadditions via Pd C(sp3)–H activation
X. Vidal, M. Font, B. Cendón, J. L. Mascareñas, M. Gulías
Trends Chem. , 2021 , 3 , 1102-1103
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41) Assembly of Tetrahydroquinolines and 2-Benzazepines by Pd-Catalyzed Cycloadditions Involving the Activation of C(sp3)–H Bonds
X. Vidal, J. L. Mascareñas, M. Gulías
Org. Lett. , 2021 , 23 , 5323–5328
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40) Rhodium(III)-catalyzed formal cycloaddition between thienopyridine/thienopyrazine carboxylic acids and alkynes, triggered by C-H activation
J. M. Rodrigues, B. Cendón, M. Gulías, J. L. Mascareñas, M. Queiroz
EurJOC , 2021 , 2021 , 3234-3240
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39) Kinetic Resolution of Allyltriflamides through a Pd-Catalyzed C–H Functionalization with Allenes: Asymmetric Assembly of Tetrahydropyridines
J. González, B. Cendón, J. L. Mascareñas, M. Gulías
J. Am. Chem. Soc. , 2021 , 143 , 3747-3752
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2020
38) Photocatalytic Trifluoromethoxylation of Arenes and Heteroarenes in Continuous-Flow
Nyuchev, A. V, Wan, T., B. Cendón, Sambiagio, C., Struijs, J. J. C, Ho, M., M. Gulías, Wang, Y. , Noël, T.
Beilstein J. Org. Chem. , 2020 , 16 , 1305–1312
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37) Palladium-catalyzed formal (4+2) cycloaddition between alkyl amides and dienes initiated by the activation of C(sp3)−H bonds
B. Cendón, M. Font, J. L. Mascareñas, M. Gulías
ACS Catal. , 2020 , 10 , 3425-3430
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2019
36) Practical, Large-Scale Preparation of Benzoxepines and Coumarins through Rhodium(III)-Catalyzed C–H Activation/Annulation Reactions
M. Gulías, D. Marcos-Atanes, J. L. Mascareñas, M. Font
Org. Process. Res. Dev. , 2019 , 23 , 1669-1673
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35) Rhodium(III)-catalyzed intramolecular annulations of acrylic and benzoic acids to alkynes
D. Fernández, N. Casanova, J. L. Mascareñas, M. Gulías
ACS Omega , 2019 , 4 , 6257−6263
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34) Palladium-catalyzed, enantioselective formal cycloaddition between benzyltriflamides and allenes: Straightforward access to enantioen-riched isoquinolines
X. Vidal, J. L. Mascareñas, M. Gulías
J. Am. Chem. Soc. , 2019 , 141 , 1862–1866
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33) Rhodium-catalyzed annulation of ortho-alkenylanilides with alkynes: Formation of unexpected naphthalene adducts
A. Seoane, C. Comanescu, N. Casanova, R. García-Fandiño, X. Diz, J. L. Mascareñas, M. Gulías
Angew. Chem. Int. Ed. , 2019 , 58 , 1700-1704
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2018
32) Iridium(I)-Catalyzed Intramolecular Cycloisomerization of Enynes: Scope and Mechanistic Course
D. Fernández, C. A. B. Rodrigues, M. Calvelo, M. Gulías, J. L. Mascareñas, F. López
ACS Catal. , 2018 , 8 , 7397–7402
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31) Enantioselective Palladium-Catalyzed [3C + 2C] and [4C + 3C] Intramolecular Cycloadditions of Alkylidenecyclopropanes
F. Verdugo, L. Villarino, J. Durán, M. Gulías, J. L. Mascareñas, F. López
ACS Catal. , 2018 , 8 , 6100-6105
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30) Rhodium(III)‐Catalyzed Annulation of 2‐Alkenylanilides with Alkynes via C‐H Activation: a Direct Access to 2‐substituted Indolines
M. Font, B. Cendón, A. Seoane, J. L. Mascareñas, M. Gulías
Angew. Chem. Int. Ed. , 2018 , 57 , 8255-8259
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2017
29) Iridium(I)-Catalyzed Intramolecular Hydrocarbonation of Alkenes: Efficient Access to Cyclic Systems Bearing Quaternary Stereocenters
D. Fernández, M. Gulías, J. L. Mascareñas, F. López
Angew. Chem. Int. Ed. , 2017 , 56 , 9641-4645
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28) Palladium-Catalyzed Formal (5 + 2) Annulation between ortho-Alkenylanilides and Allenes
B. Cendón, N. Casanova, C. Comanescu, R. García-Fandiño, A. Seoane, M. Gulías, J. L. Mascareñas
Org. Lett. , 2017 , 19 , 1674-1677
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2016
27) Concise, Enantioselective, and Versatile Synthesis of (-)-Englerin A. Based on a Platinum-Catalyzed [4C+3C] Cycloaddition of Allenedienes
R. Nelson, M. Gulías, J. L. Mascareñas, F. López
Angew. Chem. Int. Ed. , 2016 , 55 (46) , 14359-14363
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26) Metal-Catalyzed Annulations through Activation and Cleavage of C-H Bonds
M. Gulías, J. L. Mascareñas
Angew. Chem. Int. Ed. , 2016 , 55 , 11000-11019
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25) Palladium(II)-Catalyzed Annulation between ortho-Alkenylphenols and Allenes. Key Role of the Metal Geometry in Determining the Reaction Outcome
N. Casanova, K. P. Del Rio, R. García-Fandiño, J. L. Mascareñas, M. Gulías
ACS Catal. , 2016 , 6 (5) , 3349–3353
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24) Amide-Directed Formation of Five-Coordinate Osmium Alkylidenes from Alkynes
N. Casanova, M. Á. Esteruelas, M. Gulías, C. Larramona, J. L. Mascareñas, E. Oñate
Organometallics , 2016 , 35 , 91-99
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2015
23) Rhodium-Catalyzed (5+1) Annulations Between 2-Alkenylphenols and Allenes: A Practical Entry to 2,2-Disubstituted 2H-Chromenes
N. Casanova, A. Seoane, J. L. Mascareñas, M. Gulías
Angew. Chem. Int. Ed. , 2015 , 54 , 2374-2377
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2014
22) Rhodium(III)-Catalyzed Dearomatizing (3 + 2) Annulation of 2-Alkenylphenols and Alkynes
A. Seoane, N. Casanova, N. Quiñones, J. L. Mascareñas, M. Gulías
J. Am. Chem. Soc. , 2014 , 136(21) , 7607-7610
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21) Straightforward Assembly of Benzoxepines by Means of a Rhodium(III)-Catalyzed C–H Functionalization of o-Vinylphenols
A. Seoane, N. Casanova, N. Quiñones, J. L. Mascareñas, M. Gulías
J. Am. Chem. Soc. , 2014 , 136(3) , 834–837
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20) Rhodium-catalyzed Intramolecular (3+2+2) Cycloadditions between Alkylidenecyclopropanes, Alkynes and Alkenes
M. Araya, M. Gulías, I. Fernández, G. Barghava, L. Castedo, J. L. Mascareñas, F. López
Chem. Eur. J. , 2014 , 20 , 10255-10259
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19) (4+3) Cycloadditions
F. López, M. Gulías, J. L. Mascareñas
Comprehensive Organic Synthesis II. Ed: Elsevier, Volumen: 5. “Combining C-C π-Bonds” , 2014 , 5 , 595-655
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2013
18) Rhodium(III)-catalyzed intramolecular annulations involving amide-directed C-H activations: synthetic scope and mechanistic studies
N. Quiñones, A. Seoane, R. García-Fandiño, J. L. Mascareñas, M. Gulías
Chem. Sci. , 2013 , 4 , 2874-2879
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2012
17) Mechanistic study on the palladium-catalyzed (3+2) intramolecular cycloaddition of alk-5-enylidenecyclopropanes
R. García-Fandiño, M. Gulías, J. L. Mascareñas, D. Cárdenas
Dalton Trans. , 2012 , 41 , 9468-9481
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16) Reactions of an Osmium(IV) Complex with Allenedienes: Coordination and Intramolecular Cycloadditions
A. Collado, M. Á. Esteruelas, M. Gulías, J. L. Mascareñas, E. Oñate
Organometallics , 2012 , 31 , 4450-4458
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2011
15) Ruthenium-catalyzed (2+2) Intramolecular Cycloaddition of Allenenes
M. Gulías, A. Collado, B. Trillo, F. López, E. Oñate, M. Á. Esteruelas, J. L. Mascareñas
J. Am. Chem. Soc. , 2011 , 133 , 7660-7663
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14) Development of transition-metal-catalyzed cycloaddition reactions leading to polycarbocyclic systems
M. Gulías, F. López, J. L. Mascareñas
Pure App. Chem. , 2011 , 83 , 495-506
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13) Amine directed Pd(II)-catalyzed C–H bond functionalization under ambient conditions
B. Haffemayer, M. Gulías, M. J. Gaunt
Chem. Sci. , 2011 , 2 , 312-315
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12) Palladium(II)-Catalyzed C-H Bond Arylation of Electron-Deficient Arenes at Room Temperature
M. J. Tredwell, M. Gulías, N. G. Bremeyer, C. C. Johansson, B. S. Collins, M. J. Gaunt
Angew. Chem. Int. Ed. , 2011 , 50 , 1076-1079
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2010
11) Nickel-Catalyzed [3+2+2] Cycloadditions between Alkynylidenecyclopropanes and Activated Alkenes
L. Saya, G. Barghava, M. Á. Navarro, M. Gulías, F. López, I. Fernández, L. Castedo, J. L. Mascareñas
Angew. Chem. Int. Ed. , 2010 , 49 , 9886-9890
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2008
10) Oxidative Pd(II)-Catalyzed C-H Bond Amination to Carbazole at Ambient Temperature
J. Jordan-Hore, C. C. Johansson, M. Gulías, E. M. Beck, M. J. Gaunt
J. Am. Chem. Soc. , 2008 , 130 , 16184-16186
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9) Palladium-catalysed [3 + 2] cycloaddition of alk-5-ynylidenecyclopropanes to alkynes: a mechanistic DFT study
R. García-Fandiño, M. Gulías, L. Castedo, J. R. Granja, J. L. Mascareñas, D. Cárdenas
Chem. Eur. J. , 2008 , 14 , 272-281
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8) Platinum-catalyzed intramolecular [4C + 3C] cycloaddition between dienes and allenes
B. Trillo, F. López, M. Gulías, L. Castedo, J. L. Mascareñas
Angew. Chem. Int. Ed. , 2008 , 47 , 951-954
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2007
7) Palladium-catalyzed [4 + 3] intramolecular cycloaddition of alkylidenecyclopropanes and dienes
M. Gulías, J. Durán, F. López, L. Castedo, J. L. Mascareñas
J. Am. Chem. Soc. , 2007 , 129 , 11026-11027
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2006
6) Palladium-catalyzed [3+2] intramolecular cycloaddition of alk-5-enylidenecyclopropanes
M. Gulías, R. García-Fandiño, A. Delgado, L. Castedo, J. L. Mascareñas
J. Am. Chem. Soc. , 2006 , 128 , 384-385
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5) Palladium-catalyzed intramolecular [3C+2C] cycloaddition of alkylidenecyclopropanes to allenes
B. Trillo, M. Gulías, F. López, L. Castedo, J. L. Mascareñas
Adv. Synth. Catal. , 2006 , 348 , 2381-2384
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2005
4) Ligand-Induced Acceleration of the Intramolecular [3 + 2] Cycloaddition between Alkynes and Alkylidenecyclopropanes
J. Durán, M. Gulías, L. Castedo, J. L. Mascareñas
Org. Lett. , 2005 , 7 , 5693-5696
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3) Divergent reactivity of alk-5-ynylidenecyclopropanes in the presence of the first or the second generation Grubbs' catalysts
B. Trillo, M. Gulías, F. López, L. Castedo, J. L. Mascareñas
J. Organomet. Chem. , 2005 , 690 , 5609-5615
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2004
2) Regioselectivity Control in a Ruthenium-Catalyzed Cycloisomerization of Diyne-ols
B. T. Trost, M. T. Rudd, M. Gulías, P. I. Lee, A. E. Pomerantz
Org. Lett. , 2004 , 6 , 4235-4238
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2003
1) Synthesis of fused Oxabicyclic Systems by Metal-Catalyzed Intramolecular Adddition of 1,3-Cycloalkanediones to Alkynes
M. Gulías, J. R. Rodríguez, L. Castedo, J. L. Mascareñas
Org. Lett. , 2003 , 5 , 1975-1977
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